Wednesday, September 23, 2015

Silver Gelatin Developed-Out-Prints (DOPs)


Invention

·         “No single figure can be credited with the invention of the silver gelatin photographic process, which gradually became the most important photographic printing process of the twentieth century”[i]
o   Several key inventors: Peter Mawdsley, Josef Marie Eder, Giuseppe Pizzighelli, and Sir William de Wiveleslie Abney[ii]
·         Silver gelatin DOPs were developed along with the gelatin POPs in the 1840s, however, few DOPs were made from 1840-1885[iii]
·         The process requires that the paper be exposed for a short time and then, with no image visible on the paper, be placed in chemical developers until an image appears[iv]
·         Almost all iconic photographers of the 20th century used silver gelatin DOP photographic material

Important Photographers
Berenice Abbott
Hoboken Railroad Yard, NewJersey, 1935
Silver Gelatin Print

Ansel Adams
Mt. Williamson, Sierra Nevada, from Manzanar, California, negative 1944; print 1981
Gelatin Silver Print
The J. Paul Getty Museum, gift of Carol Vernon and Robert Turbin in memory of Marjorie and Leonard Vernon
 © 2014 The Ansel Adams Publishing Rights Trust

 
Richard Avedon
Allen Ginsberg and Peter Orlovsky with Brendan Behan and Beatrice ffrench-Salkeld, poets, playwright, and painter, New York, September 28, 1960, undated
Gelatin silver print
1/2 unique related prints
© The Richard Avedon Foundation

 
Henri Cartier-Bresson
Hyères, France, 1932
Gilman Collection, Purchase, Ann Tenenbaum and Thomas H. Lee Gift, 2005
The Metropolitan Museum of Art, 2005.100.460
© Henri Cartier-Bresson/Magnum



 
Man Ray
Rayograph, 1922
Gelatin silver print
Ford Motor Company Collection, Gift of Ford Motor Company and John C. Waddell, 1987
The Metropolitan Museum of Art, 1987.1100.42
© 2015 Artists Rights Society (ARS), New York 

Typical ways in which it was used

·         The silver gelatin DOP photographic process was the most important photographic printing process of the twentieth century
o   Used for all photographic and imaging applications, including:
§  art photography
§  commercial portraiture
§  documentary photography
§  in all specialized imaging tasks from criminology to scientific imaging (infrared photography and X-ray imaging)
o   It was only in the late 1960s did the number of processed color photographs exceed the production and processing of silver gelatin DOP photographs[v]
·         From the mid-1880s to just after the start of the 20th century, silver gelatin POPs, silver gelatin DOPs, and collodion POPs were in competition to replace the popular albumen prints in the marketplace
o   Since 1910, silver gelatin DOPs have dominated the market
§  Popular because of the speed of the paper and the range of colors and surface textures available[vi]

Tips on Identification

·         Dates of common use: 1890-2000[vii]
·         DOPs vs. POPs
o   DOPs have a cooler-toned paper with deep rich grays and dark blue blacks[viii]
o   POPs with have paper with warmer tones and brownish and purplish colors[ix]
·         Image Tone:
o   Over the process’s long history, silver gelatin DOPs have been toned in a variety of colors
o   Silver gelatin DOPs that have not been toned are a neutral black color
o   Common toners, popular in the 1920s and 1930s are Sepia, Polysulfide and Selenium, which produce varying shades of brown[x]
·         Deterioration:
o   Due to poor stability, early silver gelatin DOPs (late 19th and early 20th century) can often be identified by their forms of deterioration: yellowing and a loss of highlight detail
o   Silver mirroring occurs when silver originating from the image rises to the surface of the print which then forms a metallic sheen by a cyclic process called oxidative-reductive deterioration[xi]
·         Layer Structure:
o   The majority pf silver gelatin DOPs have either a baryta layer or a pigmented polyethylene layer between the emulsion and the paper support that acts to obscure paper fibers
§  Therefore, under low magnification inspection of the surface of a print, there will be an absence of visible paper fibers (however, the presence of paper fibers does not completely eliminate the print as a DOP)[xii]


Preservation Concerns
·         In response to fluctuations in the temperature preservation problems are seen with silver gelatin DOPs
o   Constant changes in temperature and relative humidity causes the gelatin surface to expand and contact which results in cockling and curling of the prints
o   Hot and dry conditions cause the gelatin emulsion to become brittle
o   Under humid conditions, the gelatin can become soft and stick to other surfaces[xiii]
·         During archival processing, hardening agents can be added to make the emulsion tougher and therefore, more resilient to moisture and temperature changes[xiv]
·         Gelatin prints require a controlled and stable environment[xv]


Bibliography

Graphic Atlas. “Identification: Silver Gelatin Developed-Out Prints (DOPs).” Image Permanence Institute, Rochester Institute of Technology, 2015. http://www.graphicsatlas.org/identification/?process_id =64.

Reilly, James M. Care and Identification of 19th Century Photographic Prints. Rochester: Eastman Kodak Co, 1986.

Ritzenthaler, Mary Lynn, and Diane Vogt-O'Connor, with Helena Zinkham, Brett Carnell, and Kit Peterson. Photographs: Archival care and management. Chicago: Society of American Archivists, 2006.

Stulik, Dusan C. and Art Kaplan. The Atlas of Analytical Signatures of Photographic Processes: Silver Gelatin. Los Angeles: J. Paul Getty Trust, 2013.



[i] Dusan C. Stulik and Art Kaplan, The Atlas of Analytical Signatures of Photographic Processes: Silver Gelatin (Los Angeles: J. Paul Getty Trust, 2013), 4.
[ii] Ibid.
[iii] James M. Reilly, Care and Identification of 19th Century Photographic Prints (Rochester: Eastman Kodak Co, 1986), 6.
[iv] Mary Lynn Ritzenthaler, and Diane Vogt-O'Connor, with Helena Zinkham, Brett Carnell, and Kit Peterson, Photographs: Archival care and management (Chicago: Society of American Archivists, 2006), 46.  
[v] Stulik and Kaplan, 27.
[vi] Ritzenthaler, et. Al, 46-47.
[vii] “Identification: Silver Gelatin Developed-Out Prints (DOPs),” Image Permanence Institute, Rochester Institute of Technology, 2015. http://www.graphicsatlas.org/identification/?process_id =64.
[viii] Stulik and Kaplan, 28.
[ix] Reilly, 5-6.
[x] “Identification: Silver Gelatin Developed-Out Prints (DOPs)”
[xi] Ibid.
[xii] Ibid.
[xiii] Ritzenthaler, et. al, 245.
[xiv] Ibid.
[xv] Ibid.

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